Charge-induced facial-selectivity in the formation of new cationic planar chiral iridacycles derived from aniline.
نویسندگان
چکیده
The reaction of chiral chlorido-iridacyclic 2-(4-N,N-dimethylaminophenyl)pyridines with solvato-type [Cp*M(S)(3)](q+) (M = Ru, S = MeCN, q = 1; M = Ir, S = MeC(O)Me, q = 2) complexes produces new cationic racemic planar chiral iridacycles in an efficient and diastereospecific way.
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 12 شماره
صفحات -
تاریخ انتشار 2011